Cationic silane sigma-complexes of ruthenium with relevance to catalysis.
نویسندگان
چکیده
Hydrosilylation of carbonyls catalyzed by 2 goes via intermediate formation of cationic silane sigma-complexes 4 which undergo nucleophilic abstraction of the silylium cation studied by DFT calculations.
منابع مشابه
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 132 17 شماره
صفحات -
تاریخ انتشار 2010